Acid Derivatives: Volume 2 (1979)

Content:
Chapter 12 Radiation chemistry of acids, esters, anhydrides, lactones and lactams (pages 755–780): O. I. Micic and O. S. Gal
Chapter thirteen The electrochemistry of carboxylic acids and derivatives: Cathodic discount rates (pages 781–824): James P. Coleman
Chapter 14 Decarbonylation reactions of acid halides and aldehydes through chlorotris?(triphenylphosphine)rhodium(i) (pages 825–857): M. C. Baird
Chapter 15 Pyrolysis of acids and their derivatives (pages 859–914): R. Taylor
Chapter sixteen Transcarboxylation reactions of salts of fragrant carboxylic acids (pages 915–944): Josef Ratusky
Chapter 17 Micellar results upon deacylation (pages 945–1020): C. A. Bunton and L. S. Romsted
Chapter 18 The chemistry of thio acid derivatives (pages 1021–1062): J. Voss
Chapter 19 The synthesis of lactones and lactams (pages 1063–1330): James F. Wolfe and Michael A. Ogliaruso

Show description

Read Online or Download Acid Derivatives: Volume 2 (1979) PDF

Best chemistry books

A text-book of inorganic chemistry,

Initially released in 1894. This quantity from the Cornell collage Library's print collections used to be scanned on an APT BookScan and switched over to JPG 2000 structure by means of Kirtas applied sciences. All titles scanned conceal to hide and pages could comprise marks notations and different marginalia found in the unique quantity.

Key Technologies in Polymer Chemistry

With contributions from specialists from either the and academia, this publication provides the newest advancements in polymer items and chemical techniques. It contains applicable case stories, explanatory notes, and schematics for extra readability and higher realizing. This new booklet: • incorporates a choice of articles that spotlight a few vital parts of present curiosity in polymer items and chemical procedures • supplies an updated and thorough exposition of the current cutting-edge of polymer chemistry • Familiarizes readers with new features of the innovations utilized in the exam of polymers, together with chemical, physicochemical, and in simple terms actual tools of exam • Describes the kinds of suggestions now to be had to the polymer chemist and technician, and discusses their features, boundaries, and purposes • offers a stability among fabrics technological know-how and mechanics elements, easy and utilized examine, and high-technology and high-volume (low-cost) composite improvement

Haloalkyne Chemistry

This publication offers effective and sensible tools for the synthesis of varied functionalized natural molecules from haloalkynes via varied response techniques akin to cross-coupling reactions, nucleophilic additions and cycloadditions. It contains 4 chapters demonstrating attention-grabbing examples of those changes, and showcasing the substitute energy of haloalkynes for quick meeting of advanced molecular buildings.

Extra resources for Acid Derivatives: Volume 2 (1979)

Example text

It was shown that the proton reduction wave of boric acid in aqueous tetraethylammonium iodide was replaced by a bigger wave at less negative potentials as small amounts of salicylic acid were added. The size of the wave could not be accounted for by the separate components and was, therefore, ascribed t o the reduction of the hydrogen atom in a complex with a higher degree of dissociation than the original acids. However, no second wave due t o aldehyde formation was observed. Robertson and collaborators3 went further and prepared mono- and disalicylborate complexes by a known method3 * .

V. Madhaven. N. N. Lichtin and E. J. Org. , 41, 2320 (1976). 70. P. Neta,J. Phys. C h e m , 75,2570 (1971). 71. N. H. Anderson, A. J. Dobbs, D. J. Edge, R. 0. C. Norman and P. R. West, J. Clrem. (B), 1004 (1971). 72. 0. P. Chaula and R. W. Fessenden, J. Pliys. , 79,76 (1975). 73. P. Neta and R. W. Fessenden,J. Phys. , 77, 620 (1973). 74. J. Lilie and R. Fessenden, J. Phys. O i e m . , 77,674 (1973). 75. R. S. Alger, T. H. Anderson and L. A. Webb, J. a i e m . , 30,695 (1959). 76. Y. Nakajima, S.

In aqueous diglyme or dioxane propionic acid was formed, but in aqueous DMSO adipic acid was the major product8 (equation 42). The direct electrochemical version of this reaction has 2 CH2CHC02H Na-Hg DMSO-HzO ' H02C(CH2)4C02H (42) 70% apparently not been pursued, although a similar reaction was observed for cinnamic acida4. The electrohydrodimerization (EHD) reaction will be discussed in more detail for carboxylic esters. Numerous other examples of double-bond hydrogenation in a$-unsaturated acids have been given in Reference 6 (p.

Download PDF sample

Rated 4.42 of 5 – based on 37 votes