Aqueous-Phase Organometallic Catalysis: Concepts and by Boy Cornils (Editor), Wolfgang A. Herrmann (Editor)

By Boy Cornils (Editor), Wolfgang A. Herrmann (Editor)

Now in its moment thoroughly revised and increased version. Written by way of the well known editors B. Cornils and W. A. Herrmann, this e-book provides each vital element of aqueous-phase organometallic catalysis, a mode which saves time, waste and funds. The large-scale software of this "green" know-how in chemical basically underlines its functional use outdoors of academia.New chapters (for instance "Organic Chemistry in Water"), 20% extra content material and completely up to date contributions from via a plethora of foreign authors make this publication a "must-have" for everybody operating during this box. From the reports of the 1st edition:"This evaluation may be super priceless for everybody lively during this box [...]" Angewandte Chemie"This booklet is a vital in any chemical examine library and that i strongly suggest it to all man made examine and educating chemists. [...]" The Alchemist"The editors are to be congratulated on assembling the sort of wide selection of members who've defined the economic in addition to the tutorial points of the subject." [...] magazine of Organometallic Chemistry

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Ost in a lecture about noxious industrial wastes, in Z. Angew. Chem. 1907, 20, 1689. [2] G. Ertl, H. Knözinger, J. ), Handbook of Heterogeneous Catalysis, VCH, Weinheim, 1997, 3 volumes. [3] R. Schlögl, Angew. Chem. 1993, 105, 402. [4] J. M. Thomas, K. I. Zamaraev, Angew. Chem. 1994, 106, 316. [5] (a) B. Cornils, W. A. ), Applied Homogeneous Catalysis with Organometallic Compounds, VCH, 1996, 2 Volumes; 2nd Ed. 2002; (b) cf. [5 a], p. 5. [6] (a) Anonymous, Nachr. Chem. Tech. Lab. 1979, 27, 257; (b) J.

M. Bregeault, A. Deloffre, J. Mol. Catal. A 1998, 133, 255; (t) G. Pozzi, I. Colombani, M. Miglioli, F. Montanari, S. Quici, Tetrahedron 1997, 53, 6145; (u) B. Boyer, A. Hambardzoumian, G. Lamaty, A. -P. Roque, P. Bouchet, New J. Chem. 1996, 20, 985; (v) E. Mizushima, K. Sato, T. Hayashi, M. Tanaka, Angew. , Int. Ed. 2002, 41, 4563; (w) B. Zimmermann, J. Herwig, M. Beller, Angew. , Int. Ed. 1999, 38, 2372; (x) K. Fuji, T. Morimoto, K. Tsutsumi, K. Kakiuchi, Angew. , Int. Ed. 2002, 42, 2409. [47] (a) F.

Rh). Water not only dissolves the catalyst, but also acts as a moderator [22, 26]; this represents the decisive difference in relation to the chemical reaction of the hydroformylation process and the process control of the reaction. The “standard ligand” of aqueous biphase catalysis, triphenylphosphine trisulfonate (TPPTS, 3,3’,3’’-phosphinidynetris[benzenesulfonic acid], trisodium salt; cf. 1), has particular significance here. To what extent the replacement of TPPTS by new ligands in the catalyst system has repercussions for the management of the aqueous biphase reaction will depend on their nature and possibly also the addition of additives and auxiliaries (cf.

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