C-X Bond Formation by Kilian Muñiz (auth.), Arkadi Vigalok (eds.)

By Kilian Muñiz (auth.), Arkadi Vigalok (eds.)

Kilian Muñiz: Transition steel Catalyzed Electrophilic Halogenation of C-H bonds in alpha-Position to Carbonyl teams; Arkadi Vigalok and Ariela W Kaspi: past due Transition Metal-Mediated Formation of Carbon-Halogen Bonds; Paul Bichler and Jennifer A. Love: Organometallic techniques to Carbon-Sulfur Bond Formation; David S. Glueck: contemporary Advances in Metal-Catalyzed C-P Bond Formation; Andrei N. Vedernikov: C-O Reductive removal from excessive Valent Pt and Pd facilities; Lukas Hintermann: contemporary advancements in Metal-Catalyzed Additions of Oxygen Nucleophiles to Alkenes and Alkynes; Moris S. Eisen: Catalytic C-N, C-O and C-S bond formation promoted by means of organoactinide complexes.

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3 Reactions with Alkenes . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 57 4 Summary and Conclusion . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 59 References . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 59 P. A. ca 40 P. A. Love Abbreviations % Acac AcOH atm BINAM ÆBINAP [bmim][OTf] Bn Bu C–S CH3CN cod Conv.

3 Reactions with Alkenes . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 57 4 Summary and Conclusion . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 59 References . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 59 P. A. ca 40 P. A. Love Abbreviations % Acac AcOH atm BINAM ÆBINAP [bmim][OTf] Bn Bu C–S CH3CN cod Conv.

Use of polar aprotic solvents or solid-supported Cu precursors provided aryl iodides from the corresponding bromides in high yields. The use of aryl chlorides instead of bromides resulted in significantly reduced reactivity. By using the isotopically labeled Na*I as a source of iodide, the copper-catalyzed reverse halide exchange was also successfully applied to the synthesis of 131I-enriched peptides in aqueous solutions [15]. In 2002, Klapars and Buchwald reported a catalytic method for converting aryl bromides into the iodides in quantitative yields and under relatively mild reaction conditions [16].

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