By Prof. Dr. D. Klemm, Prof. Dr. B. Philipp, Dr. T. Heinze, Dr. U. Heinze, Dr. W. Wagenknecht(auth.)
Cellulose is not just an immense constituent of wooden and ordinary fabric fibers. It additionally serves as a polymeric beginning fabric for items utilized in many parts of and every-day-life.
The e-book, written by way of prime specialists within the box, is split in to volumes:
within the first quantity common info on cellulose constitution and homes is given in addition to the rules of homogeneous and heterogenous cellulose reactions and degradation pathways. Analytical equipment for the characterization of cellulose also are described.
the second one quantity covers man made routes to a few of the periods of cellulose derivatives. dependent in keeping with the rules of natural chemistry the achievements of contemporary response thought are thought of and supplemented by means of an in depth number of operating strategies. It additionally offers with the newest advancements and destiny developments in cellulose chemistry - from growth in cellulose processing to the supramolecular chemistry of recent derivatives of cellulose.
This large insurance makes the e-book a customary paintings for graduate scholars coming into this interesting box of analysis, but in addition chemists, biologists and engineers who're energetic in chemical processing of cellulose will discover a wealth of knowledge.
Chapter 4.1–4.1.4 Systematics of Cellulose Functionalization: part 4.1–4.1.4 (pages 1–31):
Chapter 4.2–188.8.131.52 Systematics of Cellulose Functionalization: part 4.2–184.108.40.206 (pages 31–51):
Chapter 4.2.3–4.2.7 Systematics of Cellulose Functionalization: part 4.2.3–4.2.7 (pages 51–71):
Chapter 4.3–4.3.6 Systematics of Cellulose Functionalization: part 4.3–4.3.6 (pages 71–99):
Chapter 4.4–220.127.116.11 Systematics of Cellulose Functionalization: part 4.4–18.104.22.168 (pages 99–145):
Chapter 4.4.2–22.214.171.124 Systematics of Cellulose Functionalization: part 4.4.2–126.96.36.199 (pages 145–164):
Chapter 4.4.3–188.8.131.52 Systematics of Cellulose Functionalization: part 4.4.3–184.108.40.206 (pages 164–197):
Chapter 4.4.4 Systematics of Cellulose Functionalization: part 4.4.4 (pages 197–207):
Chapter 4.5–4.5.1 Systematics of Cellulose Functionalization: part 4.5–4.5.1 (pages 207–210):
Chapter 4.5.2–220.127.116.11 Systematics of Cellulose Functionalization: part 4.5.2–18.104.22.168 (pages 210–249):
Chapter 4.5.3–22.214.171.124 Systematics of Cellulose Functionalization: part 4.5.3–126.96.36.199 (pages 249–262):
Chapter 4.5.4–188.8.131.52 Systematics of Cellulose Functionalization: part 4.5.4–184.108.40.206 (pages 262–273):
Chapter 4.5.5–220.127.116.11 Systematics of Cellulose Functionalization: part 4.5.5–18.104.22.168 (pages 274–294):
Chapter 4.5.6 Systematics of Cellulose Functionalization: part 4.5.6 (pages 294–302):
Chapter 4.6–4.6.2 Systematics of Cellulose Functionalization: part 4.6–4.6.2 (pages 302–314):
Chapter 5.1–5.5 destiny advancements in Cellulose Chemistry – An Outlook: part 5.1–5.5 (pages 315–325):
Read or Download Comprehensive Cellulose Chemistry: Functionalization of Cellulose, Volume 2 PDF
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Extra resources for Comprehensive Cellulose Chemistry: Functionalization of Cellulose, Volume 2
Fig. 11 gives an example of the increase of mass of the sample due to grafting by the two-step technique in dependency on radiation dose in the preirradiation step at otherwise constant reaction conditions. A steep increase of add-on occurs already at a rather low dose, followed by a levelling-off. This indicates the advantage of a rather low irradiation dose for an efficient grafting, while a further increase of the dose mainly promotes chain scission without improving the graft yield. In order to secure a high efficiency of grafting, the transition time between pre-irradiation and grafting must be kept short, as the add-on is proportional to the actual radical concentration and decreases steeply with increasing transition time (Fig.
9). After crosslinking with formaldehyde via short acetal bridges, a continuous decrease in water retention value (WRV) with increasing degree of crosslinking can be observed. 1 Formation and Modification of the Polymer Skeleton of Cellulose gree of crosslinking. 3). It is interesting to note that the susceptibility to enzymatic or acid hydrolysis of glycosidic bonds also passed a distinct maximum with increasing degree of crosslinking. Crosslinking, especially with formaldehyde or formaldehyde urea compounds, affects decisively the mechanical properties of cellulose fibers and threads.
Polym. Bull. 1980, 3, 407-413. , Polym. Bull. 1982, 6, 321-326 and 583-588. , Carbohydr. Polym. 1996, 3l, 11-18. , /. Macromol. Sci-Chem. 1976, A 10, 737-757. , Papier (Darmstadt) 1996, 50, 293-299. , in The Chemistry and Technology of Cellulosic Copolymer, Berlin: Springer Verlag, 1981. , in Technologie der Strahlenchemie von Polymeren, Berlin: Akademie Verlag, 1990. , Acta Polym. 1990, 41, 259-269. , /. Appl Polym. Sei. 1977, 27, 2991-3002. , Polym. Bull. 1989, 22, 89-94. , /. -Chem. 1976, AlO, 671-679.