Practical Inorganic Chemistry by Spitsyn V.I. (ed.), Vorobyova O.J., Dunaeva K.M.

By Spitsyn V.I. (ed.), Vorobyova O.J., Dunaeva K.M.

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In order to mimic the natural systems and to test the relevant factor governing the self-organization, the self-assembly of synthetic model chromophores has been studied extensively in non-polar organic solvents and in micro-heterogeneous media, like for example aqueous micellar solutions. Chlorosomes give characteristically broad and red-shifted Qy absorption bands which stem from the longest wavelength absorption band of (B)Chls. f. Fig. 14). In contrast, within the chlorosome and upon self-assembly this maximum is strongly red-shifted to 740–760 nm [71, 72].

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